2-(Tritylsulfan­yl)ethyl 3-iodo­benzoate

نویسندگان

  • Xin Zhu
  • Seik Weng Ng
چکیده

The triphenyl-methyl group in the title compound, C(28)H(23)IO(2)S, has the methine carbon slightly flattened out [ΣC(phen-yl)-C-C(phen-yl) = 332.8 (6) °]. The -C-O-C-C-S- chain connecting the triphenyl-methyl group and the aromatic ring adopts an extended zigzag conformation, these five atoms being approximately co-planar (r.m.s. deviation 0.260 Å).

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

2-(Tritylsulfan­yl)ethyl 2-iodo­benzoate

The methine C atom of the triphenyl-methyl group in the title compound, C(28)H(23)IO(2)S, is slightly flattened out [ΣC(phen-yl)-C-C(phen-yl) = 335.6 (5)°]. The -C-O-C-C-S- chain connecting the triphenyl-methyl group and the aromatic ring adopts an extended zigzag conformation, these five atoms lying on an approximate plane (r.m.s. deviation = 0.120 Å).

متن کامل

Cyclo­propylammonium 4-iodo­benzoate

In the title mol-ecular salt, C(3)H(8)N(+)·C(7)H(4)IO(2) (-), the cyclo-propanaminium cation forms three hydrogen bonds to the 4-iodo-benzoate anion, forming two unique repeating R(4) (4)(12) hydrogen-bonding rings that result in one-dimensional hydrogen-bonded columns along the crystallographic c axis.

متن کامل

N-Trityl-2-(tritylsulfan­yl)aniline

The title compound, C(44)H(35)NS, is a derivative of amino-thio-phenol and possesses a protected S-triphenyl-methyl thio-ether and an N-triphenyl-methyl-amine functional group. The trityl groups show an anti orientation, with C-C-N-C and C-C-S-C torsion angles of -151.0 (3) and -105.3 (2)°, respectively. There is an intra-molecular N-H⋯S hydrogen bond.

متن کامل

1-{[4′-(1H-1,2,4-Triazol-2-ium-1-ylmeth­yl)biphenyl-4-yl]meth­yl}-1H-1,2,4-triazol-2-ium bis­(3-carb­oxy-5-iodo­benzoate)–5-iodo­benzene-3,5-dicarb­oxy­lic acid–water (1/2/2)

The neutral carb-oxy-lic acid mol-ecule and the carboxyl-ate anion in the title compound, C(18)H(18)N(6) (2+)·2C(8)H(4)IO(4) (-)·2C(8)H(5)IO(4)·2H(2)O, are both nearly planar (r.m.s. deviations = 0.034 and 0.045 Å, respectively). In the cation, the mid-point of the C-C bond linking the two benzene rings lies on a center of inversion, and the triazole ring is approximately perpendicular to the a...

متن کامل

Condensation reactions of 3-oxo-2-arylhydrazonopropanals with active methylene reagents: formation of 2-hydroxy- and 2-amino-6-substituted-5-arylazonicotinates and pyrido[3,2-c]cinnolines via 6π-electrocyclization reactions.

3-Oxo-3-phenyl-2-(p-tolylhydrazono)propanal (1a) undergoes condensation with ethyl cyanoacetate in acetic acid in the presence of ammonium acetate to yield either 2-hydroxy-6-phenyl-5-p-tolylazonicotinic acid ethyl ester (6a) or 2-amino-6-phenyl-5-ptolyl-azonicotinic acid ethyl ester (8), depending on the reaction conditions. Similarly, other 3-oxo-3-aryl-2-arylhydrazonopropanals 1a,b condense ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011